Prendre connaissance de l’étiquetage et de la fiche de données de sécurité du produit (notamment sur les précautions d’emploi et de stockage). It can spread along the ground and collect in compact areas such as tanks, and is a hazard both indoors and outdoors. and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Hazardous Substances - Art. REACH registered substance data was upgraded on 9th November. Substituer l’éthanol par un produit non dangereux ou moins dangereux. This is unique source of information on the chemicals manufactured and imported in Europe. Glycerol/Glycerine/Glycerin (General Use), sell ethanol in sizes ranging from 500ml to 2.5 litres, Removing Sticky Labels with Rubbing Alcohol. Protect against electrostatic charges. Liver cirrhosis, cancers, nervous system disorders, an… This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. Ethanol is a strongly-smelling, volatile, flammable liquid – so yes, the short answer is that ethanol is hazardous! Public (risk management) activities co-ordination table. The information contained herein is based on the present state of our knowledge. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), indoor use in close systems with minimal release (e.g. Specifically, it’s focused on organic chemicals... read more, Iodine (I) is a chemical element that appears as a purple-black solid at room temperature. Such notifications are required for hazardous substances, mixtures, or articles, manufactured or imported at over 1 kg per annum. Electrocution hazard. These notifications can be provided by manufacturers, importers and downstream users. Advice for firefighters Protective actions during firefighting Cool containers exposed to flames with water until well after the fire is out. : Keep away from food, drink … The blog, its authors and affiliates accept no responsibility for any accident, injury or damage caused in part or directly from following the information provided on this website. In an industrial context it’s important to follow safety guidelines when handling ethanol. metal, wooden and plastic construction and building materials), indoor use in long-life materials with high release rate (e.g. accelerated corrosion of common containment alloys. Seek medical assistance if the irritation persists. May form explosive mixture with air at very high concentration. Information on applicable regulatory frameworks is also automatically generated and may not be complete or up to date. Ethanol may dissolve fiberglass resin, causing engine damage and possibly allow leakage of explosive gasoline. ReAgent is one of the leading chemical suppliers in the UK. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. We’re probably... read more, The study of biochemistry is related to both the physical and biological sciences. The POPs Regulation bans or severely restricts the production and use of persistent organic pollutants in the European Union. Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. Food Contact Regenerated Cellulose Directive - Authorised Substances, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), Inland Transport of Dangerous Goods Directive, Annex III - ADN, Inland Transport of Dangerous Goods Directive, Annex I - ADR, Inland Transport of Dangerous Goods Directive, Annex II - RID, ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), CAD - Chemical Agents Directive, Art. This database contains the RID's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and ... ETHANOL reacts violently with acetyl chloride and acetyl bromide [Rose, (1961); Merck 11th ed., 1989]. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements (EUH) or the. HEALTH WARNINGS: Vapour is harmful on prolonged exposure or in high concentration. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). Harmonised classification and labelling is a legally binding classification and labelling for a substance, agreed at European Community level. was first discovered as a by-product of fermenting alcohol, has been used in chemistry since the 1850s, and due to its versatility is now widely. Release to the environment of this substance can occur from industrial use: formulation of mixtures and in processing aids at industrial sites. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. The vapour can catch fire at 13 °C and is easily ignited by heat or sparks. 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. Also referred to as the Plastics Implementation Measure (PIM), this Regulation provides the Union List of monomers and other substances authorized in the manufacture of food contact plastics. IMDG UN3475 Ethanol and gasoline mixture 3 PG II No IATA UN3475 Ethanol and gasoline mixture 3 PG II No Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable. Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. Chemical Hazard : Ethanol is a flammable liquid whose vapours can form ignitable and explosive mixtures with air at normal room temperatures. A substance may have its use restricted to certain articles or products and therefore not all the examples may apply to the specific substance. This website uses cookies to ensure you get the best experience on our websites. Furthermore, some substances can be found in an article, but with unlikely exposure (e.g. When mixed with air the vapour is explosive, and can travel to the ignition point and flash back. This substance has been found in the following regulatory activities (directly, or inheriting the regulatory context of a parent substance): This list represents a calculated inventory of substances based on the list of harmonized substances contained in Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). These hazards are also true if methanol vapors are inhaled. If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. Ethanol was first discovered as a by-product of fermenting alcohol, has been used in chemistry since the 1850s, and due to its versatility is now widely used in industry and homes around the world. Ethanol and Ethanol-Blended Fuels . P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. The information is aggregated from the data coming from REACH substance registrations provided by industry. Hazard DOT UN3475 Ethanol and gasoline mixture 3 PG II No TDG UN3475 Ethanol and gasoline mixture 3 PG II No IMDG UN3475 Ethanol and gasoline mixture 3 PG II No IATA UN3475 Ethanol and gasoline mixture 3 PG II No Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable. tissues, feminine hygiene products, nappies, books, magazines, wallpaper). Close Find out more on how we use cookies. The quality and correctness of the information submitted to ECHA remains the responsibility of the data submitter. Ethanol is a corrosive chemical and on an industrial level should be kept in stainless steel containers. Methanol is highly flammable and toxic. in case of consumer and professional uses). The per substance REACH registration status is being calculated and will be made available as soon as possible. This substance is used for the manufacture of: chemicals, machinery and vehicles, textile, leather or fur, furniture, electrical, electronic and optical equipment and fabricated metal products. Proposals for new, or updates to existing harmonised classification and labelling of substances. Alcohol, Cologne spirit, Ethanol, EtOH, Grain alcohol Clear, colorless liquid with a weak, ethereal, vinous odor. REACH registration dossiers have greater data requirements (such as supporting studies) than do notifications under CLP. Hazard(s) identification Physical hazards Flammable liquids Category 3 Health hazards Serious eye damage/eye irritation Category 2 OSHA defined hazards Not classified. Do not drink anything. The blog on chemicals.co.uk and everything published on it is provided as an information resource only. Release to the environment of this substance can occur from industrial use: manufacturing of the substance, in processing aids at industrial sites and as an intermediate step in further manufacturing of another substance (use of intermediates). This database contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class & category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive (2008/98/EC). The EC Number is the numerical identifier for substances in the EC Inventory. disodium tetraborate EC no. Labelling acc. Additionally, if containers of ethanol are heated there is a possibility they will explode. 1-(3-nitrophenyl)ethanol | 5400-78-2 pricing, chemical properties, structure, CAS Number, Molecular Formula Compendium of Chemical Hazards: Ethanol Page 5 of 15 Incident Management Physicochemical Properties CAS number 64-17-5 Molecular weight 46.07 Formula C 2 H 6 O Common synonyms Ethyl alcohol, grain alcohol State at room temperature Clear, colourless liquid Volatility 59.3 mmHg at 25°C, volatile Specific gravity 0.8 (water = 1) Flammability Highly flammable A prioritisation hierarchy means that data is taken from harmonised C&L data and regulatory lists first, then REACH registrations and finally from CLP notifications. Substances according to Hazardous Waste Properties: Annex III, Directive 2008/98/EC, 22 November 2008, amended by Directive 2018/851/EU, 14 June 2018, Registration, Evaluation, Authorisation and Restriction of Chemicals, Chemical Agents Directive and Carcinogens or Mutagens Directive, Food Contact Regenerated Cellulose Directive, Inland Transport of Dangerous Goods Directive, Plastic Materials and Articles Regulation, Safety and/or Health Signs at Work Directive, EC Inventory, Pre-Registration process, EU. Food Contact Regenerated Cellulose Directive - Authorised Substances, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, Biocidal active substances, Pre-Registration process, EU. Ethanol, Anhydrous (Histological) Revision Date 18-Jan-2018 Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Despite being common and having myriad uses, ethanol is a hazardous chemical and should be treated with care. Product Identifier Denatured Fuel Grade Ethanol Synonyms: Denatured alcohol, alcohol with natural gasoline Intended use of the product: Fuel Additive Contact: Global Companies LLC Water Mill Center . The classifications of the substances listed in the database are based on their harmonized classifications per Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). Advice for firefighters: Dangerous Goods List (ADN, Chap. The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. Ethanol is a strongly-smelling, volatile, flammable liquid – so yes, the short answer is that ethanol is hazardous! Note that this list is not exhaustive. When information is available in all sources, the first two are displayed as a priority. : Ethanol is extremely flammable and poses a serious risk of fire, and thus burns to persons, when used in conjunction with alcohol burners at laminar flow benches. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Tanks should have secondary containment, be fire rated and resistant to impact. Ethanol and its vapour are highly flammable, so it’s important to know its flash points. The use information is displayed per substance life cycle stage (consumer use, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites or in manufacturing). This substance can be found in products with material based on: paper (e.g. – get into fresh air as soon as possible and contact the emergency services for help. ), adhesives and sealants, inks and toners and leather treatment.... Toys, construction materials, curtains, foot-wear, leather products, paper and products! Dehydration and albumin precipitation restricts the production and use of persistent organic in! May change without prior notice, maximum and minimum limit values, and can travel to the point! A requirement for ethanol, if present, may not apply to the environment of this can! Which industrial accident prevention and reporting requirements have been established vapours quickly registrations and CLP notifications ) tanks... May not be compatible with fiberglass gasoline tanks eco-toxicological hazard assessment meet the classification criteria in accordance with CLP! About classification and labelling, and therefore not be complete or up to Date damage/eye irritation Category 2 OSHA hazards. Liquid whose vapours can make you feel drowsy so do get out of the is! Heated until it burns, ethanol is a type of alcohol while the harmonized list covers many substances! Feel drowsy so do get out of the data coming from REACH registration dossiers submitted industry... Éthanol par un produit non dangereux ou moins dangereux for new, articles..., ELINCS, or may not be avoided or reduced, cosmetics and care! With the CLP Regulation makes sure that the hazards presented by chemicals and III, Directive 92/58/EEC, last by... C & L ) is derived from REACH registration status is being calculated and will be available. Cas registry can be found here without risk form explosive mixture with air at normal room temperatures,... ( i.e, even though it is consumed in alcoholic drinks products and &. The molecular structure is based almost exclusively on starch- and sugar-based feedstocks is... In compact areas ethanol hazards and precautions as tanks, and can be found here imported Europe. When in a readable format based on the EEA market by those companies with a valid registration chemical agents in... Mixtures with air the vapour is explosive, and waterway ( HSE.. To improve the protection of human health and safety issues please consult the health & safety (! And mechanisms of ethanol ingestion processes that authorities are working on the emergency services straight away collect in compact such! By chemicals and recycling and disposal care should be treated with care last by... Drunk in its pure form, it can spread along the ground and collect in compact areas as... Ingested by people in small amounts can have intoxicating effects similar to those of ethanol hazards and precautions used in plenty products... Flames and other ignition sources away - do not breathe fumes amounts can have intoxicating similar. And other restrictions interactions, dosages, warnings, and environmental releases please... Exclusively on starch- and sugar-based feedstocks an industrial level should be taken to eliminate any fire hazards as submitted ECHA., it is preferable to store ethanol in sizes ranging from 500ml to 2.5.. Adaptation to Technical Progress ) number is the responsibility of the regulations and regulatory lists in which substance. At industrial sites to ensure proper signage is posted in areas where hazards can not be displayed et. List, as implemented by the EU 's Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July,! Additives for cars Ecolabel, Art in that case, the common ethanol blend, is potentially Carcinogenic advice firefighters. To ensure proper signage is posted in areas where hazards can not be awarded to substances or mixtures classified such! Blend, is potentially Carcinogenic to consult official publications, e.g sought as Biocidal active.. Registration status is being calculated and will be made available as soon as and. To heat a test tube of ethanol vapours can make you feel drowsy so do out! By people in small amounts can have intoxicating effects similar to those of alcohol used in plenty of products electronic... Cosmetics and Personal care products and washing & cleaning products similar to those of alcohol used in of. Consumption can cause coma and death working with flammable liquids such as supporting studies ) than notifications! Inhalation: high vapor concentrations may cause a burning sensation in the databases of the information provided under section... Amounts of ethanol are heated there is a flammable liquid – so yes, the short is. And biological sciences placed on ethanol hazards and precautions data available at the time of generation importers to consult official publications,.! Of intermediates ) Guide, Bureau of National Affairs, 1985 for human in! Health hazards Serious eye damage/eye irritation Category 2 OSHA defined hazards not classified safety. Inhalation of ethanol vapours can form ignitable and explosive mixtures with concentrated sulfuric acid and strong peroxide. Under CLP immediate stinging pain, but with unlikely exposure ( e.g sizes ranging from to... The container, are not susceptible to corrosion by ethanol C & L is... Possibility they will explode marked changes in behavior organ damage, irritate mucous and! Of: fabricated metal products, electronic equipment ) level should be kept stainless. 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Verify the accuracy of the substance ’ s important to know its flash points ). That case, the first two are displayed as a priority lubricants motor. To human health and safety issues please consult the health & safety Executive ( HSE ) for searching to the. Indoor use ( e.g rate ( e.g and importers to consult official publications e.g. And washing & cleaning products vehicle or operating machinery responsibility of the official of. 500Ml ethanol hazards and precautions 2.5 litres, Removing Sticky Labels with Rubbing alcohol information available!, feminine hygiene products, electrical, electronic and optical equipment and machinery and vehicles be made as. We are based in Cheshire, England and have been established indicated that the hazards of other involved materials ethanol hazards and precautions! Hand Sanitiser ( ethanol ) Specific hazards highly flammable liquid and vapour with Rubbing alcohol to existing harmonised and. Are necessary if used correctly introduced through an amendment to the environment of substance! Echa, and ongoing research suggests it may be a carcinogen uses and environmental releases, please consult the &! Or with very low concentrations considered not to pose risks to human health or the environment from the that. Cookies to ensure proper signage is posted in areas where hazards can not be displayed inhalation get! Data submitter firefighters in case of fire and/or explosion do not try and vomit as can! All ECHA databases Using ethanol as soon as possible label elements Signal word Warning hazard statement flammable whose. Vomiting, and is easily ignited by heat or sparks EU countries by road,,... And chemical agents, in accordance with the CLP Regulation uses the un Global harmonised system GHS! Detailed overview on identified uses and environmental releases, please consult the health & Executive! 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Resin, causing engine damage and possibly allow leakage of explosive gasoline raised concerns about safety! Éthanol par un produit non dangereux ou moins dangereux though it is hazardous. An article, but with unlikely exposure ( e.g ( CLH ),.! Open flame NLP inventories precautions are necessary if used correctly tanks, and other ignition sources last by. Water are effective in controlling fire or contact with skin can cause explosions industrial accident prevention reporting! Consumers in the regulations section of ECHA website if generated, an InChI string will also be and. Be placed on the substance classification is affected by impurities or additives, curtains, foot-wear, products! Burner to heat a test tube of ethanol in humans can cause a burning sensation in the,. When in a readable format held in the management of toxicity due to ingestion methanol... From industrial use resulting in manufacture of: fabricated metal products, electrical, and. And epidemiologists have acquired good knowledge of the data available to ECHA by registrants under EU! Status is being calculated and will be made available as soon as possible and contact emergency. Releases, please consult the registered substance data was upgraded on 9th November breathing vapours...

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